As transitgeoff said it will just flake off unless you prep the surface, it could look cool

depending on what colour your van is now and what colour metalflake your planning on using.
I think you need to give a few more details or even post a couple of pics of your van and some of the colour of metalflake that your thinking of using.
Edit: One idea that you could try before painting your van would be to get an old body panel, paint it the same colour as your van then spray on the metalflake so you can see what it looks like yourself.

Blue 1998 Ford transit 2.5di 70ps 120 swb low roof Mk5 with 5 seats. 1.5 turns on pump, egr butterfly removed and a stainless steel Urban X funnel air filter fitted. Now happily burning SVO.