It's about time somebody put a mechanical pump on a Duratorq
As you've said, pulley will need sorting and while both pumps are out, attention to timing to be clarified
Also check the height of the pump, just in case it interferes with the plastic inlet manifold
The firing order is different between DI and Duratorq
(should be straight forward to correct)
The lever that operates the pump is on the wrong side of the pump (pump fits on the opposite side of engine) so this will need sorting
I also think that the late Di s injectors work on very similar pressures as the Duratorq, so can't see that being a problem
Don't understand why your speedo won't work though
Late MK5s use electronic speedos
Unless you have the digital mileometer display, then this may well be very different)
And yes, ALL that wiring, ALL those sensors, ECU and EGR system can be dumped