Yep the split charger will work in both directions if you use a common chassis earth, whichever battery reads over the threshhold it'll switch on
If it's just trickle a charge for in storage i'd only use a 5A charger, (tis what i use) Ctek are great, i have a 30A on mine for shore power, i use solar to trickle for storage but obv with no sun that's not happening, i have 400W on the roof and some days i still get nothing at all but any kind of sun for over an hour and my whole system will reach float BUT it's a lot of solar for just keeping batterys topped up in storage ! i usually use a minimum of 50W per battery just in case, you can't have too much solar, only too little but it's allways a compromise between covering your arse in winter and having way more than needed in summer, you never get it fully balenced, i strive for surviving winter and just accepting i have too much in the summer and some power is waisted.
If i was setting up similar to yours i would put solar on the leasure and charger on the starter same as you've done, with the common ground durite sharing power no matter what battery is full.
One thing i notice with the victron MPPT is it wont start to charge untill the solar input voltage is at or over 18V (5V over battery voltage) so if you have low voltage solar pannles like 18 to 25v OCV you might find on overcast days the voltage is too low to get anything, that's where a PWM charge controller wins, as soon as the panel voltage is higher than the battery voltage it'll charge, so you may need higher voltage panels with the victron MPPT ?